Abstract
Neutron-diffraction studies of show that a second-order structural phase transition occurs at K involving transverse atomic displacements with wave vector . The electronic transport properties of the most nearly stoichiometric crystals show that is a semimetal with /. Small impurity concentrations or deviations from stoichiometry reduce , increase , and suppress the phase transition. This reduction together with the observed displacement pattern lead us to speculate that the transition is driven by an electron-hole coupling.
- Received 18 June 1976
DOI:https://doi.org/10.1103/PhysRevB.14.4321
©1976 American Physical Society