Abstract
The Bose-Einstein condensation of excitons continues to garner immense attention as a prototypical example for observing emergent properties from many-body quantum effects. In particular, titanium diselenide () is a promising candidate for realizing exciton condensation and was experimentally observed only very recently [Kogar et al., Science 358, 1314 (2017)]. Surprisingly, the condensate was experimentally characterized by a soft plasmon mode that only exists near the transition temperature of the charge density wave (CDW). Here, we characterize and analyze the experimental spectra using linear-response time-dependent density functional theory and find that the soft mode can be attributed to interband electronic transitions. At the CDW state below , the periodic lattice distortions hamper the spontaneous formation of the exciton by introducing a CDW gap. The band gap raises the soft mode and merges it into the regular plasmon. Our surprising results contradict previous simplistic analytical models commonly used in the scientific literature. In addition, we find that a finite electronic temperature introduces a dissipation channel and prevents the condensation above . The combined effect of the CDW and explains the fragile temperature dependence of the exciton condensation. Taken together, our work provides the first ab initio atomic-level framework for rationalizing recent experiments and further manipulating exciton condensates in .
- Received 12 July 2019
- Revised 19 October 2019
DOI:https://doi.org/10.1103/PhysRevB.100.205423
©2019 American Physical Society