Isotope shifts and transition frequencies for the S and P states of lithium: Bethe logarithms and second-order relativistic recoil

L. M. Wang, Chun Li, Z.-C. Yan, and G. W. F. Drake
Phys. Rev. A 95, 032504 – Published 17 March 2017

Abstract

Isotope shifts and total transition frequencies are calculated for the 2S23S2 transition of the lithium isotopes Li6, Li7, Li8, Li9, and the halo nucleus Li11. The accuracy is improved for previously calculated relativistic and quantum electrodynamic corrections, and in particular a disagreement for the Bethe logarithm is resolved for the ground S2 state. Our previous result is confirmed for the 2P2 state. We use the pseudostate expansion method to perform the sum over virtual intermediate states. Results for the second-order relativistic recoil term of order α2(μ/M)2 Ry are shown to make a significant contribution relative to the theoretical uncertainty, but because of accidental cancellations the final result for the isotope shift is nearly unchanged. However, the spin-orbit term makes an unexpectedly large contribution to the splitting isotope shift (SIS) for the 2P1/222P3/22 fine structure, increasing the theoretical value for the Li6Li7 isotopes to 0.55631(7)±0.001 MHz. A comparison is made with high-precision measurements and other calculations for the SIS and for the total 2S23S2 transition frequency.

  • Received 30 January 2017

DOI:https://doi.org/10.1103/PhysRevA.95.032504

©2017 American Physical Society

Physics Subject Headings (PhySH)

Atomic, Molecular & Optical

Authors & Affiliations

L. M. Wang1, Chun Li2, Z.-C. Yan3,4, and G. W. F. Drake5

  • 1Department of Physics, Henan Normal University, Xinxiang, Henan 453007, People's Republic of China
  • 2Department of Mathematics, Nanjing University, Nanjing 210093, China
  • 3Department of Physics, University of New Brunswick, Fredericton, New Brunswick, Canada E3B 5A3
  • 4State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China and Center for Cold Atom Physics, Chinese Academy of Sciences, Wuhan 430071, China
  • 5Department of Physics, University of Windsor, Windsor, Ontario, Canada N9B 3P4

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Issue

Vol. 95, Iss. 3 — March 2017

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