Abstract
Isotope shifts and total transition frequencies are calculated for the transition of the lithium isotopes , and the halo nucleus . The accuracy is improved for previously calculated relativistic and quantum electrodynamic corrections, and in particular a disagreement for the Bethe logarithm is resolved for the ground state. Our previous result is confirmed for the state. We use the pseudostate expansion method to perform the sum over virtual intermediate states. Results for the second-order relativistic recoil term of order Ry are shown to make a significant contribution relative to the theoretical uncertainty, but because of accidental cancellations the final result for the isotope shift is nearly unchanged. However, the spin-orbit term makes an unexpectedly large contribution to the splitting isotope shift (SIS) for the fine structure, increasing the theoretical value for the isotopes to MHz. A comparison is made with high-precision measurements and other calculations for the SIS and for the total transition frequency.
- Received 30 January 2017
DOI:https://doi.org/10.1103/PhysRevA.95.032504
©2017 American Physical Society