Finite-field calculation of static polarizabilities and hyperpolarizabilities of In+ and Sr

Yan-mei Yu, Bing-bing Suo, Hui-hui Feng, Heng Fan, and Wu-Ming Liu
Phys. Rev. A 92, 052515 – Published 23 November 2015

Abstract

The dipole polarizabilities, dipole hyperpolarizabilities, quadrupole moments, and quadrupole polarizabilities of the 5s2S1 and 5s5p3Po states of In+ and Sr are calculated by using the finite-field method. The electron correlation effect and the basis set convergence are investigated in the relativistic coupled-cluster and configuration interaction calculations in order to obtain polarizabilities of high accuracy. Comparative study of the fully and scalar relativistic calculations reveals the effect of the spin-orbit coupling on the dipole polarizabilities of In+ and Sr. The blackbody-radiation shifts of the clock transition 5s21S05s5fp3P0o due to the dipole polarizabilities, quadrupole polarizabilities, and dipole hyperpolarizabilities are evaluated to be 0.017, 8.33×1010, and 1.93×1017 Hz for In+ and 2.09 and 5.82×108, and 1.69×1015 Hz for Sr. The blackbody-radiation shifts from the quadrupole polarizabilities and dipole hyperpolarizabilities are significantly less than that from the dipole polarizabilities and therefore can be safely omitted for the quoted 1018 uncertainty of the optical frequency standard of In+ and Sr.

  • Received 12 January 2015
  • Revised 22 October 2015

DOI:https://doi.org/10.1103/PhysRevA.92.052515

©2015 American Physical Society

Authors & Affiliations

Yan-mei Yu1,*, Bing-bing Suo2,†, Hui-hui Feng1, Heng Fan1, and Wu-Ming Liu1

  • 1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • 2Institute of Modern Physics, Northwest University, Xi'an, Shanxi 710069, China

  • *ymyu@aphy.iphy.ac.cn
  • bsuo@nwu.edu.cn

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Vol. 92, Iss. 5 — November 2015

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