Abstract
The electric-dipole and quadrupole polarizabilities of the state and the and coefficients for the and dimers of strontium are calculated using a high-precision relativistic approach that combines configuration interaction and linearized coupled-cluster methods. Our recommended values of the long-range dispersion coefficients for the and energy levels are a.u. and a.u., respectively. They are in good agreement with recent results from experimental photoassociation data. We also calculate coefficients for Sr dimers, which are needed for precise determination of long-range interaction potential. We confirm the experimental value for the magic wavelength, where the Stark shift on the transition vanishes. The accuracy of calculations is analyzed and uncertainties are assigned to all quantities reported in this work.
- Received 21 September 2014
DOI:https://doi.org/10.1103/PhysRevA.90.052715
©2014 American Physical Society