Relativistic calculations of C6 and C8 coefficients for strontium dimers

S. G. Porsev, M. S. Safronova, and Charles W. Clark
Phys. Rev. A 90, 052715 – Published 18 November 2014

Abstract

The electric-dipole and quadrupole polarizabilities of the 5s5p3P1o state and the C6 and C8 coefficients for the 1S0+1S0 and 1S0+3P1o dimers of strontium are calculated using a high-precision relativistic approach that combines configuration interaction and linearized coupled-cluster methods. Our recommended values of the long-range dispersion coefficients for the 0u and 1u energy levels are C6(0u)=3771(32) a.u. and C6(1u)=4001(33) a.u., respectively. They are in good agreement with recent results from experimental photoassociation data. We also calculate C8 coefficients for Sr dimers, which are needed for precise determination of long-range interaction potential. We confirm the experimental value for the magic wavelength, where the Stark shift on the 1S03P1o transition vanishes. The accuracy of calculations is analyzed and uncertainties are assigned to all quantities reported in this work.

  • Received 21 September 2014

DOI:https://doi.org/10.1103/PhysRevA.90.052715

©2014 American Physical Society

Authors & Affiliations

S. G. Porsev1,2, M. S. Safronova1,3, and Charles W. Clark3

  • 1Department of Physics and Astronomy, University of Delaware, Newark, Delaware 19716, USA
  • 2Petersburg Nuclear Physics Institute, Gatchina, Leningrad District, 188300, Russia
  • 3Joint Quantum Institute, National Institute of Standards and Technology and the University of Maryland, Gaithersburg, Maryland 20899, USA

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Issue

Vol. 90, Iss. 5 — November 2014

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