Atomic properties of Cd-like and Sn-like ions for the development of frequency standards and search for the variation of the fine-structure constant

M. S. Safronova, V. A. Dzuba, V. V. Flambaum, U. I. Safronova, S. G. Porsev, and M. G. Kozlov
Phys. Rev. A 90, 052509 – Published 13 November 2014

Abstract

A high-precision relativistic calculation of Cd-like Nd12+,Sm14+ and Sn-like Pr9+,Nd10+ atomic properties is carried out using an approach that combines configuration interaction and a linearized coupled-cluster method. These ions have long-lived metastable states with transitions accessible by laser excitations, relatively simple electronic structure, high sensitivity to α variation, and stable isotopes. Breit and QED corrections were included into the calculations. Energies, transition wavelengths, electric- and magnetic-multipole reduced matrix elements, lifetimes, and sensitivity coefficients q and K to the variation of the fine-structure constant α were obtained. A detailed study of uncertainties was performed. Energies for similar Cd-like Ba8+,La9+,Ce10+,Pr11+ and Sn-like Ba6+ ions were calculated and compared with experiment for further tests of the accuracy.

  • Received 22 September 2014

DOI:https://doi.org/10.1103/PhysRevA.90.052509

©2014 American Physical Society

Authors & Affiliations

M. S. Safronova1,2, V. A. Dzuba3, V. V. Flambaum3, U. I. Safronova4,5, S. G. Porsev1,6, and M. G. Kozlov6,7

  • 1University of Delaware, Newark, Delaware 19716, USA
  • 2Joint Quantum Institute, NIST and the University of Maryland, College Park, Maryland 20742, USA
  • 3The University of New South Wales, Sydney, Australia
  • 4University of Nevada, Reno, Nevada 89503, USA
  • 5University of Notre Dame, Notre Dame, Indiana 46556, USA
  • 6Petersburg Nuclear Physics Institute, Gatchina 188300, Russia
  • 7St. Petersburg Electrotechnical University “LETI” St. Petersburg 197376, Russia

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Issue

Vol. 90, Iss. 5 — November 2014

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