Abstract
Exact analytical expressions of the dipole polarizabilities of the nonrelativistic hydrogen atom in spherical coordinates are derived with the help of the Lagrange-mesh numerical method. This method can provide exact energies and wave functions for well-chosen conditions of calculation. Exact dipole polarizabilities are obtained after an unambiguous rounding up to at least principal quantum numbers around . The scalar polarizability of any level is given by and its tensor polarizability is given by , which allows the calculation of the polarizability of any hydrogen state .
- Received 6 November 2012
DOI:https://doi.org/10.1103/PhysRevA.86.062514
©2012 American Physical Society