Exact nonrelativistic polarizabilities of the hydrogen atom with the Lagrange-mesh method

Daniel Baye
Phys. Rev. A 86, 062514 – Published 26 December 2012

Abstract

Exact analytical expressions of the dipole polarizabilities of the nonrelativistic hydrogen atom in spherical coordinates are derived with the help of the Lagrange-mesh numerical method. This method can provide exact energies and wave functions for well-chosen conditions of calculation. Exact dipole polarizabilities are obtained after an unambiguous rounding up to at least principal quantum numbers around n=30. The scalar polarizability of any nl level is given by n4[4n2+14+7l(l+1)]/4 and its tensor polarizability is given by n4[3n29+11l(l+1)]l/4(2l+3), which allows the calculation of the polarizability of any hydrogen state nlm.

  • Received 6 November 2012

DOI:https://doi.org/10.1103/PhysRevA.86.062514

©2012 American Physical Society

Authors & Affiliations

Daniel Baye*

  • Physique Quantique, Code Postal 165/82, and Physique Nucléaire Théorique et Physique Mathématique, Code Postal 229, Université Libre de Bruxelles (ULB), B 1050 Brussels, Belgium

  • *dbaye@ulb.ac.be

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Vol. 86, Iss. 6 — December 2012

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