Abstract
Strong hybridization, resulting in symmetric and antisymmetric mixing of the Zn 3 state and the 4 state of symmetry, is found in the jellium-based local density approximation (LDA) structure of the Zn@ ground state. Using the time-dependent LDA method to include electron correlations, the photoionization of these - hybrid states are computed. Ionization cross sections of these states exhibit effects of plasmon resonances coupled with the diffraction-type oscillations induced by localized emissions of electrons. We detect significant interference effects in the hybrid ionization from the atom-fullerene coherent mixing.
- Received 21 August 2012
DOI:https://doi.org/10.1103/PhysRevA.86.053201
©2012 American Physical Society