Abstract
In an earlier study, the exchange energy density has been calculated analytically for Ne-like atomic ions in the nonrelativistic limit of large atomic number Z. Here, though now by numerical methods based on the optimized exchange potential approximation, corresponding results are obtained for for such ten-electron ions at large Z. The approach to the bare Coulomb limiting form of the expansion is considered in some detail, as are corrections to the Slater potential given in terms of the exchange energy density and ground-state density by
- Received 8 April 2003
DOI:https://doi.org/10.1103/PhysRevA.68.044502
©2003 American Physical Society