Abstract
To support efforts on cooling and trapping of alkaline-earth-metal atoms and designs of atomic clocks, we performed ab initio relativistic many-body calculations of electric-dipole transition amplitudes between low-lying states of Mg, Ca, and Sr. In particular, we report amplitudes for for and for transitions. For Ca, the reduced matrix element is in good agreement with a high-precision experimental value deduced from photoassociation spectroscopy [Zinner et al., Phys. Rev. Lett. 85, 2292 (2000)]. An estimated uncertainty of the calculated lifetime of the state of Mg is a factor of 3 smaller than that of the most accurate experiment. Calculated binding energies reproduce experimental values within
- Received 20 February 2001
DOI:https://doi.org/10.1103/PhysRevA.64.012508
©2001 American Physical Society