Linearized bivariational coupled-cluster approach: General scheme for derivation of static properties

Sourav Pal
Phys. Rev. A 39, 2712 – Published 1 March 1989
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Abstract

The recently developed bivariational coupled-cluster approach was earlier used for the derivation of equations for first-order properties in a two-body approximation. In this paper we introduce a linearized form of this approach in which the bra vector is linearized. In such a form the bivariational coupled-cluster approach reduces to the nonvariational-response-type approach, and thus it can also be more easily generalized to any higher-order property in a more extended approximation. This also gives us an alternative variational derivation of the original nonvariational-response equations of Monkhorst.

  • Received 3 October 1988

DOI:https://doi.org/10.1103/PhysRevA.39.2712

©1989 American Physical Society

Authors & Affiliations

Sourav Pal

  • Physical Chemistry Division, National Chemical Laboratory, Pune 411 008, India

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Vol. 39, Iss. 5 — March 1989

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