Abstract
For electrons moving independently in a -dimensional bare point-charge potential, the Euler equation of density-functional theory in the limit of large numbers of electrons, , is combined with the virial theorem to relate the sum of eigenvalues to the chemical potential . The result is . This result (I) is verified by direct calculation of both and for in the asymptotic limit of large . Neither does there seem to be any difficulty in applying (I) for . But evidently for ; an immediate consequence of the virial theorem for this dimensionality. Viewed as a continuous function of , is singular at and is negative for . Excluding this pathological regime of , it can be shown from (I) that, for a point charge , , where the exponent is given by (I).
- Received 10 May 1984
DOI:https://doi.org/10.1103/PhysRevA.30.2936
©1984 American Physical Society