Abstract
Optical characteristics of have been determined from 0.02 to 14 eV. Single crystals were used for measurements above 0.05 eV. The shift with temperature of the crystal-field splitting peak is shown to be reasonably attributed to the effect of magnetic ordering. A broad weak band near 1 eV may be either an impurity band or the unallowed transition . The absorption edge at 2.8 eV is explained as due to transitions from the wide band to the narrow band. Two tiny peaks in the edge at 2.96 and 3.05 eV are suggested to be zero-phonon spin-orbit-split exciton peaks associated with this transition. High-energy absorption structure taken from Kramers-Kronig analysis of ultraviolet reflectance data are assumed to be associated with wide-band to wide-band transitions as in nonmagnetic compounds. A simple band diagram is suggested to explain the electronic transitions. The reststrahlen reflectance on a pressed powder was analyzed and the following parameters obtained: low- and high-frequency dielectric constants, 20 and 6.8; longitudinal and transverse optical mode frequencies, 320 and 185 .
- Received 3 November 1966
DOI:https://doi.org/10.1103/PhysRev.156.989
©1967 American Physical Society