Abstract
The occurrence of metallic conductivity in single crystals is reported for reduction under low partial pressure of oxygen at . This transition is shown to result from the formation of a high concentration of vacancy defects along a network of extended defects within the skin region. A self-healing phenomenon is observed for progressive reduction which causes the concentration of initially introduced defects to decrease in the course of heat treatment and leads to a breakdown of the metallic conductivity as well as a substantial loss of optical subgap absorption.
- Received 25 June 2001
DOI:https://doi.org/10.1103/PhysRevLett.88.075508
©2002 American Physical Society