Interferometric Signatures of Single Molecules

We built an interferometer where one of the two slits of a classical Young's setup is replaced by a single molecule embedded in a solid matrix. This enabled direct measurement of the first order coherence of the 0-0 single-molecule emission, which at high excitation powers proves to be split in coherent and incoherent parts. We demonstrate an order of magnitude higher precision in axial localization of single molecules in comparison with that of confocal microscopy. These experiments open a possibility for single-molecule holography. Detection of single molecules with low luminescence quantum yields could be another application of this technique.