C13 NMR Chemical Shift of Single-Wall Carbon Nanotubes

Sylvain Latil, Luc Henrard, Christophe Goze Bac, Patrick Bernier, and Angel Rubio
Phys. Rev. Lett. 86, 3160 – Published 2 April 2001
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Abstract

We compute the magnetic shielding tensor within the London approximation and estimate the Knight shift of single-wall carbon nanotubes. Our results indicate that high resolution 13C NMR should be able to separate the metallic and insulator character of the nanotubes since a 11 ppm splitting is predicted from the respective resonances. As a model for disorder, bending, and defects in these structures, we investigate the magnetic response of nanotubes with finite size. We get a small line broadening coming from an intrinsic length dependent resonance effect. The nanotube packing is also studied and leads to a 20 ppm broadening which disappears under experimental high-resolution conditions.

  • Received 8 August 2000

DOI:https://doi.org/10.1103/PhysRevLett.86.3160

©2001 American Physical Society

Authors & Affiliations

Sylvain Latil1, Luc Henrard2, Christophe Goze Bac1, Patrick Bernier1, and Angel Rubio3

  • 1Groupe de Dynamique des Phases Condensées, CNRS-Université de Montpellier 2, France
  • 2Laboratoire de Physique du Solide, Facultés Universitaires Notre-Dame de la Paix, Namur, Belgium
  • 3Donostia International Physics Center (DIPC) and Centro Mixto CSIC-UPV/EHU, 20018 San Sebastián/Donostia, Basque Country, Spain

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Issue

Vol. 86, Iss. 14 — 2 April 2001

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