Abstract
We investigate the highly frustrated spin and orbital superexchange interactions in cubic vanadates. The fluctuations of orbitals trigger a novel mechanism of ferromagnetic interactions between spins of ions along one of the cubic directions which operates already in the absence of Hund's rule exchange , and leads to the -type antiferromagnetic phase in . The Jahn-Teller effect can stabilize the orbital ordering and the -type antiferromagnetic phase at low temperatures, but large entropy due to orbital fluctuations favors again the phase at higher temperatures, as observed in .
- Received 11 October 2000
DOI:https://doi.org/10.1103/PhysRevLett.86.3879
©2001 American Physical Society