Spin Order due to Orbital Fluctuations: Cubic Vanadates

Giniyat Khaliullin, Peter Horsch, and Andrzej M. Oleś
Phys. Rev. Lett. 86, 3879 – Published 23 April 2001
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Abstract

We investigate the highly frustrated spin and orbital superexchange interactions in cubic vanadates. The fluctuations of t2g orbitals trigger a novel mechanism of ferromagnetic interactions between spins S=1 of V3+ ions along one of the cubic directions which operates already in the absence of Hund's rule exchange JH, and leads to the C-type antiferromagnetic phase in LaVO3. The Jahn-Teller effect can stabilize the orbital ordering and the G-type antiferromagnetic phase at low temperatures, but large entropy due to orbital fluctuations favors again the C phase at higher temperatures, as observed in YVO3.

  • Received 11 October 2000

DOI:https://doi.org/10.1103/PhysRevLett.86.3879

©2001 American Physical Society

Authors & Affiliations

Giniyat Khaliullin1, Peter Horsch1, and Andrzej M. Oleś1,2

  • 1Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany
  • 2Institute of Physics, Jagellonian University, Reymonta 4, PL-30059 Kraków, Poland

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Vol. 86, Iss. 17 — 23 April 2001

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