Abstract
We present an analytical theory of stress relaxation in monodisperse linear polymer melts that contains contributions from both reptation and contour-length fluctuations, modeled as in our previous work on arm retraction in star polymers. Our approach resolves two long-standing problems with reptation theory: it predicts a zero-shear viscosity scaling as over a broad range in chain length before reaching an asymptotic dependence, and a power law in the dynamic loss modulus with depending on chain length, in agreement with experiment.
- Received 14 January 1998
DOI:https://doi.org/10.1103/PhysRevLett.81.725
©1998 American Physical Society