Equilibrium properties of a diblock copolymer lamellar phase confined between flat plates

Matthew S. Turner
Phys. Rev. Lett. 69, 1788 – Published 21 September 1992
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Abstract

We study theoretically the equilibrium behavior of the lamellar phase of an A-B diblock copolymer melt. Each lamellar layer is an A-B,B-A repeat unit and n such layers are confined between, and parallel to, two identical flat plates. We find that the configurations with a half-odd-integer number of layers occur only when the difference between the two polymer-plate surface tensions is small, and then only below some critical plate separation. We calculate the discontinuity in the pressure at the transition point between two different values of n.

  • Received 24 June 1992

DOI:https://doi.org/10.1103/PhysRevLett.69.1788

©1992 American Physical Society

Authors & Affiliations

Matthew S. Turner

  • Institut Charles Sadron, 6 rue Boussingault, 67083 Strasbourg CEDEX, France

Comments & Replies

Comment on “Equilibrium Properties of a Diblock Copolymer Lamellar Phase Confined between Flat Plates”

Navjot Singh, Frank S. Bates, and Matthew Tirrell
Phys. Rev. Lett. 75, 976 (1995)

Turner Replies:

Matthew S. Turner
Phys. Rev. Lett. 75, 977 (1995)

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Issue

Vol. 69, Iss. 12 — 21 September 1992

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