Abstract
Anisotropic surface diffusion of CO on Ni(110) has been studied using the newly developed technique of optical second-harmonic diffraction from a laser-induced CO monolayer grating. Two distinct orthogonal diffusion channels, along [11¯0] and [001], were found. The measured diffusion coefficients yield the diffusion activation energies (11¯0)=1.1±0.2 kcal/mol and (001)=3.1±0.4 kcal/mol and the preexponential factors (11¯0)=(3.8±2.0)× /sec and (001)=(4.8±4.4)× /sec. The anisotropy in the surface diffusion appears to cross over at T∼160 K.
- Received 17 December 1990
DOI:https://doi.org/10.1103/PhysRevLett.66.2352
©1991 American Physical Society