Abstract
Picosecond infrared excitation experiments on acetanilide, an α-helix protein analog, indicate that the anomalous 1650- band which appears on cooling of acetanilide crystals persists for at least several microseconds following rapid pulsed heating. The ground-state recovery time is 15±5 psec, consistent with a conventional mode strongly coupled to the phonon bath. We therefore suggest that the unusual temperature-dependent spectroscopy of acetanilide can be accounted for by slightly nondegenerate hydrogen atom configurations in the crystal.
- Received 2 June 1989
DOI:https://doi.org/10.1103/PhysRevLett.64.607
©1990 American Physical Society