Elastic Anomaly and Phase Transition of BaTiO3

T. Ishidate and S. Sasaki
Phys. Rev. Lett. 62, 67 – Published 2 January 1989
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Abstract

The acoustic-phonon velocities of a single crystal of BaTiO3 have been measured as a function of pressure up to 8 GPa, including the transition pressure pc=2.35 GPa, by means of Brillouin scattering technique. Only one elastic eigenmode shows an anomalous decrease on approaching pc and the elastic anisotropy increases. The elastic anomaly of cubic BaTiO3 is interpreted well by introducing a new tensorial order parameter which describes the anisotropy. The cubic-to-tetragonal phase transition in BaTiO3 is shown to be triggered by the fluctuation of the anisotropy, not the polarization itself.

  • Received 26 August 1988

DOI:https://doi.org/10.1103/PhysRevLett.62.67

©1989 American Physical Society

Authors & Affiliations

T. Ishidate and S. Sasaki*

  • Department of Physics, Faculty of Science, Shizuoka University, Ohya, Shizuoka 422, Japan

  • *Present address: Department of Electronics and Computer Engineering, Gifu University, Yanagido, Gifu 501-11, Japan.

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Vol. 62, Iss. 1 — 2 January 1989

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