Complete phase diagram of a charged colloidal system: A synchro- tron x-ray scattering study

E. B. Sirota, H. D. Ou-Yang, S. K. Sinha, P. M. Chaikin, J. D. Axe, and Y. Fujii
Phys. Rev. Lett. 62, 1524 – Published 27 March 1989
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Abstract

High-resolution, small-angle, synchrotron x-ray-scattering techniques were used to determine the phase diagram, structure factor, and pair distribution function for a charged colloidal suspension from 6% to 30% volume fraction. The expected correlated liquid and fcc and bcc solid phases were observed along with a glass phase at high concentration with structure similar to metallic glasses. At high volume fractions the finite core size leads to substantial deviation from predictions resulting from a screened Coulomb interaction.

  • Received 5 December 1988

DOI:https://doi.org/10.1103/PhysRevLett.62.1524

©1989 American Physical Society

Authors & Affiliations

E. B. Sirota, H. D. Ou-Yang, S. K. Sinha, and P. M. Chaikin

  • Exxon Research and Engineering Co., Rt. 22 East, Annandale, New Jersey 08801
  • Department of Physics, University of Pennsylvania, Philadelphia, Pennsylvania 19104
  • Department of Physics, Princeton University, Princeton, New Jersey 08544

J. D. Axe and Y. Fujii

  • Brookhaven National Laboratory, Upton, New York 11973

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Issue

Vol. 62, Iss. 13 — 27 March 1989

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