Abstract
High-resolution, small-angle, synchrotron x-ray-scattering techniques were used to determine the phase diagram, structure factor, and pair distribution function for a charged colloidal suspension from 6% to 30% volume fraction. The expected correlated liquid and fcc and bcc solid phases were observed along with a glass phase at high concentration with structure similar to metallic glasses. At high volume fractions the finite core size leads to substantial deviation from predictions resulting from a screened Coulomb interaction.
- Received 5 December 1988
DOI:https://doi.org/10.1103/PhysRevLett.62.1524
©1989 American Physical Society