Freeze-Fracture Electron-Microscope Observations of the Blue Phase III

J. A. N. Zasadzinski, S. Meiboom, M. J. Sammon, and D. W. Berreman
Phys. Rev. Lett. 57, 364 – Published 21 July 1986
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Abstract

Transmission-electron microscopy of chiral 4-(2-methylpentylphenyl)-4′-hexyloxybenzoate (CE4) quenched from its cholesteric and blue phases (BP) I and III are presented. Images of cholesteric and BP I are consistent with an earlier study of similar compounds. CE4 quenched from its BP III is a spaghettilike tangle of filamentary objects of 10- to 50-nm diameter and lengths of 0.1 to 1 μm. These are likely double-twist cylinders in a liquidlike arrangement, melted from their lattice structure in the BP I and II. BP III apparently has a basic, double-twisted structure whose sense and length scale correspond to BP I and BP II, but without the latter's long-range periodicity.

  • Received 28 March 1986

DOI:https://doi.org/10.1103/PhysRevLett.57.364

©1986 American Physical Society

Authors & Affiliations

J. A. N. Zasadzinski, S. Meiboom, M. J. Sammon, and D. W. Berreman

  • AT&T Bell Laboratories, Murray Hill, New Jersey 07974

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Issue

Vol. 57, Iss. 3 — 21 July 1986

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