Reply to “Comment on Test of nonequilibrium thermodynamics in glassy systems: The soft-sphere case”

E. La Nave, F. Sciortino, P. Tartaglia, M. S. Shell, and P. G. Debenedetti
Phys. Rev. E 71, 033102 – Published 25 March 2005

Abstract

We show that Gupta’s Comment is incorrect, since the equilibration process in question is not isothermal, and hence the free energy does not decrease. We furthermore show that our free energy expression [E. La Nave, F. Sciortino, P. Tartaglia, M. S. Shell, and P. G. Debenedetti, Phys. Rev. E 68, 032103 (2003)] satisfies the second law.

  • Received 21 September 2004

DOI:https://doi.org/10.1103/PhysRevE.71.033102

©2005 American Physical Society

Authors & Affiliations

E. La Nave1,2, F. Sciortino1,2, P. Tartaglia1,3, M. S. Shell4, and P. G. Debenedetti4

  • 1Dipartimento di Fisica and INFM, Università di Roma “La Sapienza,” Piazzale Aldo Moro 2, 00185 Roma, Italy
  • 2INFM - CRS Soft, Università; di Roma “La Sapienza,” Piazzale Aldo Moro 2, 00185 Roma, Italy
  • 3INFM - CRS SMC, Università di Roma “La Sapienza,” Piazzale Aldo Moro 2, 00185 Roma, Italy
  • 4Department of Chemical Engineering Princeton University, Princeton, New Jersey 08544, USA

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Original Article

Test of nonequilibrium thermodynamics in glassy systems: The soft-sphere case

E. La Nave, F. Sciortino, P. Tartaglia, M. S. Shell, and P. G. Debenedetti
Phys. Rev. E 68, 032103 (2003)

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Issue

Vol. 71, Iss. 3 — March 2005

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