Test of nonequilibrium thermodynamics in glassy systems: The soft-sphere case

E. La Nave, F. Sciortino, P. Tartaglia, M. S. Shell, and P. G. Debenedetti
Phys. Rev. E 68, 032103 – Published 23 September 2003
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Abstract

The scaling properties of the soft-sphere potential allow the derivation of an exact expression for the pressure of a frozen liquid, i.e., the pressure corresponding to configurations which are local minima in its multidimensional potential energy landscape. The existence of such a relation offers the unique possibility for testing the recently proposed extension of the liquid free energy to glassy out-of-equilibrium conditions and the associated expression for the temperature of the configurational degrees of freedom. We demonstrate that the nonequilibrium free energy provides an exact description of the soft-sphere pressure in glass states.

  • Received 9 May 2003

DOI:https://doi.org/10.1103/PhysRevE.68.032103

©2003 American Physical Society

Authors & Affiliations

E. La Nave, F. Sciortino, and P. Tartaglia

  • Dipartimento di Fisica, INFM UdR and Center for Statistical Mechanics and Complexity, Università di Roma La Sapienza, Piazzate Aldo Moro 5, I-00185 Rome, Italy

M. S. Shell and P. G. Debenedetti

  • Department of Chemical Engineering, Princeton University, Princeton, New Jersey 08544, USA

Comments & Replies

Comment on “Test of nonequilibrium thermodynamics in glassy systems: The soft-sphere case”

Prabhat K. Gupta
Phys. Rev. E 71, 033101 (2005)

Reply to “Comment on Test of nonequilibrium thermodynamics in glassy systems: The soft-sphere case”

E. La Nave, F. Sciortino, P. Tartaglia, M. S. Shell, and P. G. Debenedetti
Phys. Rev. E 71, 033102 (2005)

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Vol. 68, Iss. 3 — September 2003

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