Generalized quantum Fokker-Planck, diffusion, and Smoluchowski equations with true probability distribution functions

Suman Kumar Banik, Bidhan Chandra Bag, and Deb Shankar Ray
Phys. Rev. E 65, 051106 – Published 3 May 2002
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Abstract

Traditionally, quantum Brownian motion is described by Fokker-Planck or diffusion equations in terms of quasiprobability distribution functions, e.g., Wigner functions. These often become singular or negative in the full quantum regime. In this paper a simple approach to non-Markovian theory of quantum Brownian motion using true probability distribution functions is presented. Based on an initial coherent state representation of the bath oscillators and an equilibrium canonical distribution of the quantum mechanical mean values of their coordinates and momenta, we derive a generalized quantum Langevin equation in c numbers and show that the latter is amenable to a theoretical analysis in terms of the classical theory of non-Markovian dynamics. The corresponding Fokker-Planck, diffusion, and Smoluchowski equations are the exact quantum analogs of their classical counterparts. The present work is independent of path integral techniques. The theory as developed here is a natural extension of its classical version and is valid for arbitrary temperature and friction (the Smoluchowski equation being considered in the overdamped limit).

  • Received 17 August 2001

DOI:https://doi.org/10.1103/PhysRevE.65.051106

©2002 American Physical Society

Authors & Affiliations

Suman Kumar Banik1, Bidhan Chandra Bag2, and Deb Shankar Ray1,*

  • 1Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700 032, India
  • 2Department of Chemistry, Visva-Bharati, Shantiniketan 731 235, India

  • *Electronic-mail: pcdsr@mahendra.iacs.res.in

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Vol. 65, Iss. 5 — May 2002

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