Ehrenfest’s argument extended to a formalism of nonequilibrium thermodynamics

Alexander N. Gorban, Iliya V. Karlin, Hans Christian Öttinger, and Larisa L. Tatarinova
Phys. Rev. E 63, 066124 – Published 24 May 2001
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Abstract

A general method of constructing dissipative equations is developed, following Ehrenfest’s idea of coarse graining. The approach resolves the major issue of discrete time coarse graining versus continuous time macroscopic equations. Proof of the H theorem for macroscopic equations is given, several examples supporting the construction are presented, and generalizations are suggested.

  • Received 14 December 2000

DOI:https://doi.org/10.1103/PhysRevE.63.066124

©2001 American Physical Society

Authors & Affiliations

Alexander N. Gorban

  • Institute of Computational Modeling RAS, 660036 Krasnoyarsk, Russia

Iliya V. Karlin*, Hans Christian Öttinger, and Larisa L. Tatarinova

  • ETH Zürich, Institute of Polymers, CH-8092 Zürich, Switzerland

  • *Corresponding author. Email address: ikarlin@ifp.mat.ethz.ch

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Issue

Vol. 63, Iss. 6 — June 2001

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