Abstract
We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio while the fluid-solid coexistence scales with the depth of the effective potential well.
- Received 5 November 1999
DOI:https://doi.org/10.1103/PhysRevE.61.R1028
©2000 American Physical Society