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Shear flow effects on phase separation of entangled polymer blends

N. Clarke and T. C. B. McLeish
Phys. Rev. E 57, R3731(R) – Published 1 April 1998
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Abstract

We introduce an entanglement model mixing rule for stress relaxation in a polymer blend to a modified Cahn-Hilliard equation of motion for concentration fluctuations in the presence of shear flow. Such an approach predicts both shear-induced mixing and demixing, depending on the relative relaxation times and plateau moduli of the two components.

  • Received 1 December 1997

DOI:https://doi.org/10.1103/PhysRevE.57.R3731

©1998 American Physical Society

Authors & Affiliations

N. Clarke and T. C. B. McLeish

  • Department of Physics and Astronomy & Interdisciplinary Research Centre in Polymer Science and Technology, University of Leeds, Leeds LS2 9JT, United Kingdom

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Vol. 57, Iss. 4 — April 1998

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