Abstract
We evaluate the equation of state of the quasi-one-dimensional (1D) phase of molecules in small carbon nanotubes, nicknamed peapods. The chemical potential and 1D pressure are evaluated as functions of the temperature and density, initially with the approximation of nearest-neighbor interactions and classical statistical mechanics. Quantum corrections and long-range interaction corrections are discussed, as are the effects of interactions with neighboring peapods. Transition phenomena involving the 3D coupling are evaluated.
- Received 28 January 2003
DOI:https://doi.org/10.1103/PhysRevB.67.205417
©2003 American Physical Society