Statistical mechanics of interacting peapods

M. Mercedes Calbi, Silvina M. Gatica, and Milton W. Cole
Phys. Rev. B 67, 205417 – Published 23 May 2003
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Abstract

We evaluate the equation of state of the quasi-one-dimensional (1D) phase of C60 molecules in small carbon nanotubes, nicknamed peapods. The chemical potential and 1D pressure are evaluated as functions of the temperature and density, initially with the approximation of nearest-neighbor interactions and classical statistical mechanics. Quantum corrections and long-range interaction corrections are discussed, as are the effects of interactions with neighboring peapods. Transition phenomena involving the 3D coupling are evaluated.

  • Received 28 January 2003

DOI:https://doi.org/10.1103/PhysRevB.67.205417

©2003 American Physical Society

Authors & Affiliations

M. Mercedes Calbi, Silvina M. Gatica, and Milton W. Cole

  • Physics Department, Pennsylvania State University, University Park, Pennsylvania 16802, USA

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Issue

Vol. 67, Iss. 20 — 15 May 2003

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