Abstract
We propose a model Hamiltonian for describing charge transport through short homogeneous double stranded DNA molecules. We show that the hybridization of the overlapping orbitals in the base-pair stack coupled to the backbone is sufficient to predict the existence of a gap in the nonequilibrium current-voltage characteristics with a minimal number of parameters. Our results are in a good agreement with the recent finding of semiconducting behavior in short - DNA oligomers. In particular, our model provides a correct description of the molecular resonances which determine the quasilinear part of the current out of the gap region.
- Received 4 March 2002
DOI:https://doi.org/10.1103/PhysRevB.65.241314
©2002 American Physical Society