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Backbone-induced semiconducting behavior in short DNA wires

Gianaurelio Cuniberti, Luis Craco, Danny Porath, and Cees Dekker
Phys. Rev. B 65, 241314(R) – Published 24 June 2002
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Abstract

We propose a model Hamiltonian for describing charge transport through short homogeneous double stranded DNA molecules. We show that the hybridization of the overlapping π orbitals in the base-pair stack coupled to the backbone is sufficient to predict the existence of a gap in the nonequilibrium current-voltage characteristics with a minimal number of parameters. Our results are in a good agreement with the recent finding of semiconducting behavior in short poly(G)-poly(C) DNA oligomers. In particular, our model provides a correct description of the molecular resonances which determine the quasilinear part of the current out of the gap region.

  • Received 4 March 2002

DOI:https://doi.org/10.1103/PhysRevB.65.241314

©2002 American Physical Society

Authors & Affiliations

Gianaurelio Cuniberti1,*, Luis Craco1, Danny Porath2, and Cees Dekker3

  • 1Max Planck Institute for Physics of Complex Systems, D-01187 Dresden, Germany
  • 2The Physical Chemistry Department, The Hebrew University of Jerusalem, IL-91904 Jerusalem, Israel
  • 3Department of Applied Physics, Delft University of Technology, NL-2628 CJ Delft, The Netherlands

  • *Email address: cunibert@mpipks-dresden. mpg. de

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Issue

Vol. 65, Iss. 24 — 15 June 2002

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