Abstract
We report Raman spectra and synchrotron x-ray diffraction measurements of lattice parameters of polycrystalline under hydrostatic pressure conditions up to 15 GPa. An anomalously broadened Raman band at is observed that exhibits a large linear pressure shift of its frequency. The large mode damping and Grüneisen parameter indicate the vibration is highly anharmonic, broadly consistent with theoretical predictions for the in-plane boron stretching mode. The results obtained may provide additional constraints on the electron-phonon coupling in the system.
- Received 16 June 2001
DOI:https://doi.org/10.1103/PhysRevB.64.100509
©2001 American Physical Society