Abstract
is one of the more promising laser hosts for micro and diode-pumped solid-state lasers. At room temperature, ions in this matrix exhibit strong absorption cross sections sixfold higher than in The neodymium oscillator strengths are measured in ( P, As), and hosts, and they increase in the sequence This paper is an attempt to correlate these variations with covalent interactions between neodymium levels and valence-band levels. The strength of orbital interactions between levels and valence-band states is estimated from the analysis of x-ray photoemission spectra of ions. A two-step model is derived, in which admixture into the levels of the rare earth occurs via the valence-band levels. This model shows that the oscillator strengths increase with the Nd -valence-band interactions.
- Received 8 September 1998
DOI:https://doi.org/10.1103/PhysRevB.60.1668
©1999 American Physical Society