Structural and radiative evolution in quantum dots near the ${\mathrm{In}}_x{\mathrm{Ga}}_{1-x}\mathrm{A}\mathrm{s}/\mathrm{G}\mathrm{a}\mathrm{A}\mathrm{s}$ Stranski-Krastanow transformation

The evolution of Stranski-Krastanow (SK) quantum-dot (QD) formation in ternary ${\mathrm{In}}_{0.6}{\mathrm{Ga}}_{0.4}\mathrm{A}\mathrm{s}/\mathrm{G}\mathrm{a}\mathrm{A}\mathrm{s}$ was studied with graded structures grown via organometallic vapor-phase epitaxy. Surface-probe microscopy showed island evolution between 3.5- and 6.5-monolayer (ML) deposition. Island densities increased exponentially (over three decades with 0.2-ML deposition) before saturation ∼4.7 ML. Photoluminescence (PL) of capped structures show that the wetting-layer PL energy does not shift beyond the onset of the SK transition. PL intensities increased with QD concentration but not in proportion to QD density. After saturation, a sharp drop in PL intensity was observed, which we attribute to island coalescence and incoherent island formation. Excitation power dependence of the luminescence at different stages of QD evolution indicates a concentration dependence of optical saturation in self-forming ${\mathrm{In}}_x{\mathrm{Ga}}_{1-x}\mathrm{As}$ QD’s.