Abstract
By slowly evaporating solutions of fullerene in 1,2-dichloroethane at room temperature, crystals of an orthorhombic 1:1 solvate are obtained [ or with and ( setting)]. Unusual decagonal needles with dihedral angles of between adjacent faces also form. They are described in terms of a twinning of these orthorhombic crystals with needle axis (or twin axis [001]) parallel to composition planes in the form whose orientations do not correspond to rational index This solvate decomposes with a desolvation enthalpy (45 kJ per mole of solvent) close to that of sublimation for pure solvent and it forms with a negative excess volume ( per formula unit). Despite a packing coefficient (0.77) higher than that for hard sphere close packing (0.74), it spontaneously decomposes at room temperature. This is related to the solvent adsorption on cubic which is shown to be preferred to the solvate formation by about per mole of solvent.
- Received 7 October 1997
DOI:https://doi.org/10.1103/PhysRevB.57.10351
©1998 American Physical Society