Abstract
The energy-resolved electron-momentum density of fullerene has been measured. Clear differences are found from the energy-momentum densities of either diamond or graphite. The energy-momentum density of fullerene can be described as being composed of a band and a split band. The observed spectral momentum densities are compared to the calculated orbitals of a C molecule in momentum space. Good agreement is found. A simple classification of the orbitals is proposed that explains elegantly the calculated and observed structures. The splitting of the band can be interpreted as a consequence of the curvature of the carbon network forming the fullerene molecule.
- Received 7 January 1997
DOI:https://doi.org/10.1103/PhysRevB.56.1309
©1997 American Physical Society