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Metallic resistivity in crystalline ropes of single-wall carbon nanotubes

J. E. Fischer, H. Dai, A. Thess, R. Lee, N. M. Hanjani, D. L. Dehaas, and R. E. Smalley
Phys. Rev. B 55, R4921(R) – Published 15 February 1997
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Abstract

Laser ablation of (Co,Ni)-doped graphite yields ∼ 70% single-wall nanotubes, predominantly (10,10) armchair tubes which self-organize into crystalline ``ropes''>100 Å in diameter and>10 μm long. We find ρ=0.03-0.10mΩ cm at 300 K, with positive (negative) dρ/dT above (below) T = 35 K. Unoriented bulk samples exhibit similar behavior, with higher (directionally averaged) resistivities and T*'s. The high-T behavior is consistent with the predicted intrinsic metallic state for this structure.

    DOI:https://doi.org/10.1103/PhysRevB.55.R4921

    ©1997 American Physical Society

    Authors & Affiliations

    J. E. Fischer1, H. Dai2, A. Thess2, R. Lee1, N. M. Hanjani1, D. L. Dehaas1, and R. E. Smalley2

    • 1Department of Materials Science and Engineering and Laboratory for Research on the Structure of Matter,
    • 2Center for Nanoscale Science and Technology, Rice Quantum Institute
    • 3Departments of Chemistry and Physics, Rice University, Houston Texas 77251

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    Vol. 55, Iss. 8 — 15 February 1997

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