Abstract
Theoretical calculations in combination with experiments for the and x-ray absorption edges are reported for graphite. Theory and experiment agree well for the leading and resonances. By comparing theoretical calculations for a single graphene layer that include the effect of the core hole to similar calculations that do not, we find that 1s x-ray absorption in graphite is to be associated with an excitonic effect. Both the and excitons are localized primarily on the core-excited atom, but have significant weight on the nearest-neighbor atoms. The results are closely related to the electronic structure of a N impurity. © 1996 The American Physical Society.
- Received 20 May 1996
DOI:https://doi.org/10.1103/PhysRevB.54.14396
©1996 American Physical Society