Magnetic phase transitions in CocMg1cCl2 and stage-2 CocMg1cCl2 graphite intercalation compounds

Itsuko S. Suzuki, Chi-Jen Hsieh, Floyd Khemai, Charles R. Burr, and Masatsugu Suzuki
Phys. Rev. B 47, 845 – Published 1 January 1993
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Abstract

Pristine CocMg1cCl2 and stage-2 CocMg1cCl2 graphite intercalation compounds (GICs) (0≤c≤1) approximate site-diluted three-dimensional (3D) and two-dimensional (2D) XY spin systems, respectively. We have studied the magnetic phase transitions of these two systems by using dc and ac magnetic susceptibilities. We find that the reduced critical temperature of stage-2 CocMg1cCl2 GIC is almost the same as that of CocMg1cCl2 for c>0.7. The effect of the dimensionality on the dilution with Mg ions becomes significant below c≊0.7. The percolation threshold for CocMg1cCl2 is cp≊0.36, close to the theoretical value (0.295) for the 2D triangular lattice with nearest-neighbor (NN) and next-nearest-neighbor (NNN) exchange interactions, and the percolation threshold for stage-2 CocMg1cCl2 GIC is cp≊0.5, close to the theoretical value (0.5) for the 2D triangular lattice with NN exchange interaction. We also find that the peak susceptibility of CocMg1cCl2 at the Néel temperature drastically increases with decreasing Co concentration. This phenomenon is discussed in terms of recent scaling theory.

  • Received 13 July 1992

DOI:https://doi.org/10.1103/PhysRevB.47.845

©1993 American Physical Society

Authors & Affiliations

Itsuko S. Suzuki, Chi-Jen Hsieh, Floyd Khemai, Charles R. Burr, and Masatsugu Suzuki

  • Department of Physics and Materials Research Center, State University of New York at Binghamton, Binghamton, New York 13902-6000

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Vol. 47, Iss. 2 — 1 January 1993

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