Abstract
Pristine and stage-2 graphite intercalation compounds (GICs) (0≤c≤1) approximate site-diluted three-dimensional (3D) and two-dimensional (2D) XY spin systems, respectively. We have studied the magnetic phase transitions of these two systems by using dc and ac magnetic susceptibilities. We find that the reduced critical temperature of stage-2 GIC is almost the same as that of for c>0.7. The effect of the dimensionality on the dilution with Mg ions becomes significant below c≊0.7. The percolation threshold for is ≊0.36, close to the theoretical value (0.295) for the 2D triangular lattice with nearest-neighbor (NN) and next-nearest-neighbor (NNN) exchange interactions, and the percolation threshold for stage-2 GIC is ≊0.5, close to the theoretical value (0.5) for the 2D triangular lattice with NN exchange interaction. We also find that the peak susceptibility of at the Néel temperature drastically increases with decreasing Co concentration. This phenomenon is discussed in terms of recent scaling theory.
- Received 13 July 1992
DOI:https://doi.org/10.1103/PhysRevB.47.845
©1993 American Physical Society