Abstract
The electronic structure of has been studied by photoemission and x-ray absorption spectroscopy. Electron doping through La substitution induces a new photoemission feature of Ti 3d character within the band gap of ; the Fermi level is located near the bottom of the conduction band of . The experimental results are incompatible with the rigid-band behavior predicted by one-electron band theory or Hubbard-model calculations.
- Received 17 August 1992
DOI:https://doi.org/10.1103/PhysRevB.46.9841
©1992 American Physical Society