Enhanced Raman scattering by fractal clusters: Scale-invariant theory

Mark I. Stockman, Vladimir M. Shalaev, Martin Moskovits, Robert Botet, and Thomas F. George
Phys. Rev. B 46, 2821 – Published 1 August 1992
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Abstract

A scale-invariant theory of Raman scattering of light by fractal clusters is developed. The enhancement factor GRS of Raman scattering is shown to scale in terms of a properly chosen spectral variable X. The critical indices of the enhancement factor are found to be determined by the optical spectral dimension of the fractal. Numerical modeling is carried out and shown to support the analytical results obtained. The theory, which does not contain any adjustable parameters, agrees well with experimental data on surface-enhanced Raman scattering over a wide spectral range.

  • Received 28 January 1992

DOI:https://doi.org/10.1103/PhysRevB.46.2821

©1992 American Physical Society

Authors & Affiliations

Mark I. Stockman

  • Departments of Physics and Chemistry, Washington State University, Pullman, Washington 99164

Vladimir M. Shalaev and Martin Moskovits

  • Department of Chemistry, University of Toronto, and Ontario Laser Lightwave Research Center, Toronto, Ontario, Canada M5S 1A1

Robert Botet

  • Laboratoire de Physique des Solides, Université Paris-Sud, Centre d’Orsay, 91405 Orsay, France

Thomas F. George

  • Departments of Physics and Chemistry, Washington State University, Pullman, Washington 99164

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Issue

Vol. 46, Iss. 5 — 1 August 1992

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