Abstract
The vibrational modes of a DNA homopolymer poly(dG)-poly(dC), where dG refers to repeating guanine bases on one strand and dC the repeating cytosine bases on the other strand, are studied at low temperature (below 77 K) by self-consistent phonon theory. We find that the modes at 84.3 and 123.9 at room temperature are shifted to 91.8 and 133.2 at low temperature. We believe these modes are important for the strand-separation melting of the DNA helix. Other modes are relatively unaffected by the same temperature change. These results are in agreement with recent infrared transmission experiments at 77 K in poly(dA)-poly(dT), where A and T stand for the adenine and thymine homopolymers.
- Received 2 February 1987
DOI:https://doi.org/10.1103/PhysRevB.36.3449
©1987 American Physical Society