High-precision calculations of van der Waals coefficients for heteronuclear alkali-metal dimers

A. Derevianko, J. F. Babb, and A. Dalgarno
Phys. Rev. A 63, 052704 – Published 12 April 2001
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Abstract

van der Waals coefficients for the heteronuclear alkali-metal dimers of Li, Na, K, Rb, Cs, and Fr are calculated using relativistic ab initio methods augmented by high-precision experimental data. We argue that the uncertainties in the coefficients are unlikely to exceed about 1%.

  • Received 29 November 2000

DOI:https://doi.org/10.1103/PhysRevA.63.052704

©2001 American Physical Society

Authors & Affiliations

A. Derevianko*, J. F. Babb, and A. Dalgarno

  • Institute for Theoretical Atomic and Molecular Physics, Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138

  • *Permanent Address: Department of Physics, University of Nevada, Reno, NV 89557.

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Vol. 63, Iss. 5 — May 2001

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