Abstract
Highly accurate Born-Oppenheimer potential-energy surfaces of were calculated and combined with multichannel quantum-defect theory (MQDT) to predict with high precision the photoionization cross section of laser-excited triatomic hydrogen recently measured in this laboratory. The experiment first prepares in stepwise excitation in a single rotational level of the symmetric stretch excited Rydberg state. One-photon ionization from this state populates the continuum and Rydberg states which autoionize into In the vicinity of the first symmetric stretch excited level of the ionization spectrum shows features similar to those observed at the lowest ionization threshold: a quasidiscrete region below the first symmetric-stretch excited threshold, a Beutler-Fano region of rotational autoionization and interlopers of low- Rydberg states belonging to high vibrationally excited cores dispersed over the continuum. The MQDT calculations include rotational, vibrational, and Jahn-Teller interactions, and permit the assignment of most of the spectral features.
- Received 6 August 1999
DOI:https://doi.org/10.1103/PhysRevA.61.033410
©2000 American Physical Society