Energy-level statistics for a relaxation Hamiltonian

Stephen L. Coy and Kevin K. Lehmann
Phys. Rev. A 36, 404 – Published 1 July 1987
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Abstract

We report a numerical computation of the energy-level spacing distribution, the spectral rigidity, and the transition-amplitude distribution for an ensemble of Hamiltonians with a single ‘‘bright’’ state interacting with a manifold of ‘‘bath’’ states. The bath states are assumed to be part of a regular spectrum so that the initial states have Poisson statistics. Despite very strong average coupling of all bath states to the bright state (which may represent coupling to another electronic surface), statistical properties of the final spectrum are more like those of the initial bath distribution than those of the Gaussian orthogonal ensemble distribution expected for an irregular quantum spectrum. The level spacings show level repulsion, but with the nonlinear threshold behavior P(s)∼s0.625.

  • Received 8 December 1986

DOI:https://doi.org/10.1103/PhysRevA.36.404

©1987 American Physical Society

Authors & Affiliations

Stephen L. Coy

  • Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138,

Kevin K. Lehmann

  • Department of Chemistry, Princeton University, Princeton, New Jersey 08544

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Vol. 36, Iss. 1 — July 1987

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