Relationship between the Schwinger and Kohn-type variational principles in scattering theory

Kazuo Takatsuka, Robert R. Lucchese, and Vincent McKoy
Phys. Rev. A 24, 1812 – Published 1 October 1981
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Abstract

We establish the correct mathematical relationship between the Schwinger and Kohn variational principles for scattering theory and show that the Schwinger principle is one rank higher than the Kohn principle. If the same trial scattering wave function is used in these two principles, the Schwinger method should hence give superior results. Application of the Schwinger and Kohn variational principles to scattering by a simple model potential gives results which clearly illustrate this relationship.

  • Received 24 October 1980

DOI:https://doi.org/10.1103/PhysRevA.24.1812

©1981 American Physical Society

Authors & Affiliations

Kazuo Takatsuka and Robert R. Lucchese

  • Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125

Vincent McKoy*

  • Zentrum für interdisziplinäre Forschung, Universität Bielefeld, D-4800 Bielefeld 1, Federal Republic of Germany

  • *Permanent address: A. A. Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125.

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Issue

Vol. 24, Iss. 4 — October 1981

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